Choose a color with the Eyedropper tool
Click on the down arrow for the color menu.
Next click in the center of the color swatch till the bucket comes up.
Once you click in the center of the Color Swatch menu, a sub menu comes up you can then name the Color Swatch.
Press ok once you rename it and then save the color swatch.
To save click the options > and choose Save Color Swatches
Rename or overwrite the current swatch.
To load another color swatch you downloaded or created just click on Load Color Swatches and choose the swatch.
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